16585-47-0Relevant academic research and scientific papers
The chloramination of some substituted stibines
McKenney, Robert L.,Sisler, Harry H.
, p. 1178 - 1182 (2007/10/18)
Trimethyl-, triethyl-, tri-n-propyl-, tri-n-butyl-, and triphenylstibines react with ammonia-free chloramine or an ammonia-chloramine mixture to produce compounds of the type [R3Sb(Cl)]2NH (I). These compounds readily hydrolyze to [R3Sb-(Cl)]2O (II ). Further reactions of II are also described. Infrared and proton magnetic resonance studies were carried out on compounds of types I and II and on a variety of other antimony compounds. Qualitative assignments of infrared bands are given.
