165877-97-4

Upstream product

• 622-30-0 N-benzyl hydroxylalmine 
• 293314-32-6 (2S,3S,4R)-4-benzylamino-1-O-tert-butyl(diphenyl)silyl-2,3-O-isopropylidene-5-(4-methoxyphenyl)pentan-1,2,3-triol 
• 606147-97-1 (2S,3S,4R)-1-O-benzyl-4-(benzylamino)-2,3-O-isopropylidene-5-(4-methoxyphenyl)pentane-1,2,3-triol 
• 152390-96-0 (Z)-N-(4-O-benzyl-1-deoxy-2,3-O-isopropylidene-L-ylidene)benzylamine-N-oxide 
• 293314-35-9 (2S,3S,4R)-4-(benzylamino)-2,3-O-isopropylidene-5-(4-methoxyphenyl)pentane-1,2,3-triol 
• 228396-51-8 {(1R)-1-(N-benzyl-N-hydroxyamino)-1-deoxy-1-(p-methoxybenzyl)-4-O-benzyl-2,3-O-isopropylidene-L-threitol} 

Downstream Products

• 27958-06-1 (2R,3S,4S)-3,4-dihydroxy-2-(4-methoxybenzyl)pyrrolidine 

Relevant academic research and scientific papers

Stereoselective synthesis of (-)-deacetylanisomycin

A stereoselective synthesis of (-)-deacetylanisomycin has been achieved from a nitrone derived from 1-threose in 6 steps and 53.7% overall yield, The key step of the synthesis is the nucleophilic addition of a Grignard derivative with complete diastereofacial selectivity. Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003.

Stereoselective synthesis of (-)-deacetylanisomycin

A concise synthesis of (-)-deacetylanisomycin has been achieved via the stereocontrolled reductive alkylation of a protected trihydroxynitrile derived from tartaric acid. The resulting aminotriol was selectively O-mesylated on the primary hydroxyl group a