165905-02-2

Basic information

• Product Name: Benzoic acid,2-(2-carboxy-3-hydroxy-5-methylphenoxy)-4-chloro-3-hydroxy-5-methoxy-, 1-methylester
• Synonyms: Pestheicacid; RES 1214-2
• CAS NO: 165905-02-2
• Molecular Formula: C17H15 Cl O8
• Molecular Weight: 382.74900
• Mol File: 165905-02-2.mol

Chemical Properties

• Melting Point: 193-197 °C
• Boiling Point: 529.6±50.0 °C(Predicted)
• Density: 1.474±0.06 g/cm3(Predicted)
• CAS DataBase Reference: Benzoic acid,2-(2-carboxy-3-hydroxy-5-methylphenoxy)-4-chloro-3-hydroxy-5-methoxy-, 1-methylester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid,2-(2-carboxy-3-hydroxy-5-methylphenoxy)-4-chloro-3-hydroxy-5-methoxy-, 1-methylester(165905-02-2)
• EPA Substance Registry System: Benzoic acid,2-(2-carboxy-3-hydroxy-5-methylphenoxy)-4-chloro-3-hydroxy-5-methoxy-, 1-methylester(165905-02-2)

Safety Data

• Hazardous Substances Data: 165905-02-2(Hazardous Substances Data)

Upstream product

• 1320259-65-1 3-chloro-4-methoxy-2-methoxymethoxy6-[(phenylmethoxy)methyl]-benzaldehyde 
• 1320259-67-3 2,6-bis(methoxymethoxy)-α-[3-chloro-4-methoxy-2-methoxymethoxy-6-[(phenylmethoxy)-methyl]]-4-methyl-benzenemethanol 
• 1320259-68-4 [2,6-bis(methoxymethoxy)-4-methylphenyl][3-chloro-4-methoxy-2-(methoxymethoxy)-6-[(phenylmethoxy)methyl]phenyl]-methanone 
• 1320259-70-8 [2,6-bis(methoxymethoxy)-4-methylphenyl][3-chloro-6-hydroxymethyl-4-methoxy-2-(methoxymethoxy)phenyl]-methanone 
• 1320259-75-3 C₂₂H₂₅ClO₉ 
• 1346458-85-2 C₂₂H₂₅ClO₁₀ 
• 1320259-72-0 methyl 2-[2,6-bis(methoxymethoxy)-4-methylbenzoyl]-4-chloro-5-methoxy-3-methoxymethoxy-benzoat 
• 1320259-48-0 2-hydroxy-4-methoxy-6-[(phenylmethoxy)methyl]-benzaldehyde 
• 1320259-78-6 3-chloro-2-hydroxy-4-methoxy-6-[(phenylmethoxy)methyl]-benzaldehyde 
• 82265-37-0 1,3-bis(methoxymethoxy)-5-methylbenzene 
• 261958-55-8 2,4-dihydroxy-6-[(phenylmethoxy)methyl]-benzaldehyde 
• 117358-51-7 1,3-difluoro-5-methylbenzene 
• 1201597-23-0 2,6-difluoro-4-methylbenzoic acid 

Relevant articles and documents

Metabolites of the higher fungi. Part 29. Maldoxin, maldoxone, dihydromaldoxin, isodihydromaldoxin and dechlorodihydromaldoxin. A spirocyclohexadienone, a depsidone and three diphenyl ethers: Keys in the depsidone biosynthetic pathway from a member of the

2-(3′-Chloro-2′-hydroxy-4′-methoxy-6′- methoxycarbonylphenoxy)-6-hydroxy-4-methylbenzoic acid (dihydromaldoxin 1), 2-(3′-chloro-4′-hydroxy-2′-methoxy-6′- methoxycarbonylphenoxy)-6-hydroxy-4-methylbenzoic acid (isodihydromaldoxin 2), dechlorodihydromaldoxi

Asymmetric Total Synthesis of (-)-Maldoxin, a Common Biosynthetic Ancestor of the Chloropupukeananin Family

The total synthesis of pestheic acid based on an intramolecular SNAr reaction without a nitro group and the asymmetric synthesis of (-)-maldoxin by a catalytic enantioselective oxidative dearomatization of pestheic acid are described. The reactivity of (-)-maldoxin as a diene in the Diels-Alder reaction is also investigated.

Syntheses of chloroisosulochrin and isosulochrin and biomimetic elaboration to maldoxin, maldoxone, dihydromaldoxin, and dechlorodihydromaldoxin

An efficient synthesis of chloroisosulochrin was accomplished using a novel ortho-selective chlorination of a phenol with sulfuryl chloride and 2,2,6,6-tetramethylpiperidine as the key step. Further elaboration by a biomimetic route converted chloroisosul