166192-42-3

Upstream product

• 154878-85-0 (1S,3aR,7S,8S,8aR,8bR)-(+)-7,8-di-tert-butoxy-1-phenyloctahydro-1H-pyrrolo<1,2-b>phospholo<2,3-d>isoxazole 1-oxide 

Downstream Products

• 166192-43-4 (2R,3S,4S)-3,4-Di-tert-butoxy-2-((1S,2R,3R)-3-methoxy-1-oxo-1-phenyl-1λ⁵-phospholan-2-yl)-1-methyl-pyrrolidine 

Relevant academic research and scientific papers

A New P-Chiral Aminophosphine Ligand Containing a 2,2'-Coupled Pyrrolidine-Phospholane Ring System. Synthesis and Coordination Properties with Rhodium(I) and Iridium(I) Fragments

A new approach to the synthesis of chiral P,N-ligands containing a stereogenic phosphorus atom is reported; the synthesis, characterization and coordination properties of (PR,2R,3R,2'R,3'S,4'S) 2-3-methoxy-1-phenyltetrahydrophosphole (P*-N-1), which contains a stereogenic phosphorus in addition to five contiguous stereocentres in the ligand backbone; compound P*-N-1 represents the first example of a new class of chiral P,N-ligands with the heteroatoms incorporated in two 2,2'-coupled pyrrolidine-phospholane rings.