166387-03-7Relevant academic research and scientific papers
Ring-closing metathesis reaction-based synthesis of new classes of polyether macrocyclic systems
Naveen,Babu, Srinivasarao Arulananda
, p. 7758 - 7781 (2015/09/08)
Ring closing metathesis (RCM) reactions of suitable substrates having terminal olefins, which are assembled from various linkers and hydroxy benzaldehydes and syntheses of a wide range of 16-30 membered, new crown ether-type polyether, aza-polyether, bis aza-polyether macrocycles and dilactone moiety embedded polyether macrocycles (macrolides) are reported. After the ring-closure reaction, installation of different functional groups and functional group modification on the periphery of the synthesized polyether/crown ether macrocycles obtained in the RCM reactions are accomplished using the epoxidation, oxidation and catalytic hydrogenation-based synthetic transformations. Along this line, the syntheses of a variety of polyether macrocycles possessing epoxide or α-hydroxy ketone or 1,2-diol functionalities at the periphery have been shown. Furthermore, the synthesized α-hydroxy ketone functionality installed polyether macrocycles were subjected to the allylation and Reformatsky type reactions to obtain homoallyl alcohol moiety-based and lactone ring-appended polyether macrocycles.
Structures of NHC Hg(II) and Ag(I) complexes and selective recognition of nitrate anion
Liu, Qing-Xiang,Zhao, Zhi-Xiang,Zhao, Xiao-Jun,Wei, Qing,Chen, Ai-Hui,Li, Hui-Long,Wang, Xiu-Guang
, p. 1358 - 1373 (2015/02/19)
A series of bis-benzimidazolium (or bis-imidazolium) salts, and their eight N-heterocyclic carbene mercury(II) and silver(I) complexes (1-8) have been synthesized and characterized. Complexes 1-4 and 6 contain similar macrometallocycles formed via one bid
Chemically induced dimerization of human nonpancreatic secretory phospholipase A2 by bis-indole derivatives
Zhou, Lu,Fang, Chao,Wei, Ping,Liu, Shiyong,Liu, Ying,Lai, Luhua
experimental part, p. 3360 - 3366 (2009/04/06)
A series of novel bis-indole compounds, 1,ω-bis(((3-acetamino-5- methoxy-2-methylindole)-2-methylene)phenoxy)alkane, have been designed and synthesized on the basis of the enzyme structure of human nonpancreatic secretory phospholipase A2 (hnps PLA2). The
