16645-68-4Relevant academic research and scientific papers
Crystal structure of K2[C2O6] - First proof of existence and constitution of a peroxodicarbonate ion
Dinnebier, Robert E.,Vensky, Sascha,Stephens, Peter W.,Jansen, Martin
, p. 1922 - 1924 (2002)
By using high-resolution X-ray powder diffraction, we have determined the first crystal structure of a peroxodicarbonate compound, synthesized by electrocrystallization at -20°C. The constitution of the peroxodicarbonate anion was established and all structural details, including its conformation (see picture), can be understood qualitatively in terms of classical concepts of the chemical bond.
ALKALI-METAL PEROXOCARBONATES, M2*nH2O2, M2, M*nH2O, AND Li2*H2O
Jones, D. Philip,Griffith, William P.
, p. 2526 - 2532 (2007/10/02)
The vibrational spectra of normal and(2)H-enriched carbonate perhydrates M2*nH2O2 (Na, n = 1.5; K, Rb, or Cs, n = 3; NH4, n = 1) and those of the normal and (13)C-enriched peroxodicarbonates M2 (M = Na, K, Rb, or Cs), normal and (13)C-enriched
