166594-33-8Relevant academic research and scientific papers
Copper-Catalyzed Oxidative C?H Bond Functionalization of N-Allylbenzamide for Regioselective C?N and C?O Bond Formation
Ranjith, Jala,Krishna, Palakodety Radha
, p. 1448 - 1451 (2019)
Copper-catalyzed oxidative couplings of N-allylbenzamides for C?N and C?O bond formations have been developed through C?H bond functionalization. To demonstrate the utility of this approach, it was applied to the synthesis of β-aminoimides and imides. To the best of our knowledge, these are the first examples in which different classes of N-containing compounds have been directly prepared from the readily available N-allylbenzamides using an inexpensive catalyst/oxidant/base (CuSO4/TBHP/Cs2CO3) system.
Metal-free synthesis of imido derivatives by direct oxidation of α-amido sulfones
Martinelli, Fabio,Palmieri, Alessandro,Petrini, Marino
experimental part, p. 5085 - 5089 (2010/10/21)
Oxidation of α-amidoaryl sulfones with m-chloroperoxybenzoic acid under mild conditions readily provides the corresponding imides in satisfactory yields. The overall processprobably involves formation of an N-acyliminium ion intermediate, which by attack
