66897-25-4

Basic information

• Product Name: 4-methoxy-N-(prop-2-en-1-yl)benzamide
• Synonyms: benzamide, 4-methoxy-N-2-propen-1-yl-; N-Allyl-4-methoxybenzamide
• CAS NO: 66897-25-4
• Molecular Formula: C₁₁H₁₃NO₂
• Molecular Weight: 191.2264
• Mol File: 66897-25-4.mol
• Article Data: 22

Chemical Properties

• Boiling Point: 348.9°C at 760 mmHg
• Flash Point: 164.8°C
• Density: 1.051g/cm³
• Vapor Pressure: 4.88E-05mmHg at 25°C
• Refractive Index: 1.522
• CAS DataBase Reference: 4-methoxy-N-(prop-2-en-1-yl)benzamide(CAS DataBase Reference)
• NIST Chemistry Reference: 4-methoxy-N-(prop-2-en-1-yl)benzamide(66897-25-4)
• EPA Substance Registry System: 4-methoxy-N-(prop-2-en-1-yl)benzamide(66897-25-4)

Safety Data

• Hazardous Substances Data: 66897-25-4(Hazardous Substances Data)

Upstream product

• 100-07-2 4-methoxy-benzoyl chloride 
• 107-11-9 1-amino-2-propene 
• 696-62-8 para-iodoanisole 
• 104-93-8 p-methylanizole 
• 100-09-4 4-methoxybenzoic acid 
• 13939-06-5 molybdenum hexacarbonyl 
• 15226-74-1 dicobalt octacarbonyl 
• 30364-57-9 4-methoxybenzoic acid 2,5-dioxo-1-pyrrolidinyl ester 

Downstream Products

• 139583-91-8 2-methyl-4-methoxybenzamide 
• 1450916-45-6 (E)-4-methoxy-N-(prop-1-en-1-yl)benzamide 
• 72432-10-1 aniracetam 
• 105-13-5 4-Methoxybenzyl alcohol 
• 319483-27-7 N-((Z)-1-{[(tert-butyl)dimethylsilyl]oxy}prop-1-enyl)-4-methoxy-N-prop-2-enylbenzamide 
• 4995-12-4 2-(4-methoxyphenyl)-1H-pyrrole 
• 3424-93-9 4-methoxyphenylacetamide 
• 255395-92-7 4-methoxy-N-propanoyl-N-prop-2-enylbenzamide 
• 66896-89-7 N-Allyl-N-(4-methoxy-benzoyl)-benzenesulfonamide 
• 100126-18-9 4-methoxy-benzoic acid-(2,3-dibromo-propylamide) 
• 99859-27-5 5-(bromomethyl)-2-(4-methoxyphenyl)-4,5-dihydrooxazole 

Relevant articles and documents

Electrochemical oxidative cyclization of: N -allylcarboxamides: Efficient synthesis of halogenated oxazolines

Herein, we reported an efficient and sustainable intramolecular electrochemical cyclization of N-allylcarboxamides for the synthesis of various halogenated oxazolines. This method was conducted in a simple undivided cell by employing lithium halogen salts

A Next-Generation Air-Stable Palladium(I) Dimer Enables Olefin Migration and Selective C?C Coupling in Air

We report a new air-stable PdI dimer, [Pd(μ-I)(PCy2tBu)]2, which triggers E-selective olefin migration to enamides and styrene derivatives in the presence of multiple functional groups and with complete tolerance of air. The same dimer also triggers extremely rapid C?C coupling (alkylation and arylation) at room temperature in a modular and triply selective fashion of aromatic C?Br, C?OTf/OFs, and C?Cl bonds in poly(pseudo)halogenated arenes, displaying superior activity over previous PdI dimer generations for substrates that bear substituents ortho to C?OTf.

Sequential catalytic carbonylation reactions for sustainable synthesis of biologically relevant entities

The sustainable synthesis of highly functionalised formylcarboxamide compounds with biological relevance is reported through a sequential aminocarbonylation/hydroformylation approach. The optimisation of palladium-catalysed aminocarbonylation of iodoaromatic substrates, using allylamine as nucleophile was first performed, with molybdenum hexacarbonyl as alternative CO source versus gaseous carbon monoxide. The combination of microwave irradiation with molybdenum hexacarbonyl allowed to selectively prepare a set of N-heterocyclic-based allylcarboxamides. Subsequent rhodium-catalysed hydroformylation of the allylcarboxamide intermediates led to the preparation of new pyridine, pyrazoline and chalcone derivatives containing both carboxamide and formyl moieties.