166769-49-9Relevant academic research and scientific papers
The reaction pathway from Speier's to Karstedt's hydrosilylation catalyst
Lappert, Michael F.,Scott, Fiona P.A.
, p. C11 - C13 (2007/10/02)
Multinuclear, variable temperature NMR spectroscopic experiments show that: (i) treatment of , 1, with an excess of (CH2=CHSiMe2)2O (LL) yields , 2; (ii) treatment of 1 with PhCH=CH2 gives 3; and (iii) reaction of cis-Pt(η
A convenient and novel route to bis(η-alkyne)platinum(0) and other platinum(0) complexes from Speier's hydrosilylation catalyst H2[PtCl6]·xH2O. X-ray structure of [Pt{(η-CH2=CHSiMe2)2O}(P-t-Bu3)]
Chandra, Grish,Lo, Peter Y.,Hitchcock, Peter B.,Lappert, Michael F.
, p. 191 - 192 (2008/10/08)
Evidence that the hydrosilylation catalyst, obtained by refluxing H2[PtCl6]·xH2O in (Me2ViSi)2O (solution A), is a Pt(0) species comprises (i) the isolation and X-ray characterization of [Rt{(η-CH2CHMe2Si)2O}(P-t-Bu3)], after addition of P-t-Bu3 to A, (ii) the convenient high-yield synthesis of various other Pt(0) complexes from A, and (iii) CV, GC/MS, and 195Pt NMR data.
