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166772-09-4

chloro(η(5)-cyclopentadienyl)[N-(trimethylsilylmethylthio-κS)-1-phenylmethanimine-1-thiolato-κS]cobalt(III) is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 166772-09-4 Structure

  • Basic information

    1. Product Name: chloro(η(5)-cyclopentadienyl)[N-(trimethylsilylmethylthio-κS)-1-phenylmethanimine-1-thiolato-κS]cobalt(III)
    2. Synonyms:
    3. CAS NO:166772-09-4
    4. Molecular Formula:
    5. Molecular Weight: 414.013
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 166772-09-4.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: chloro(η(5)-cyclopentadienyl)[N-(trimethylsilylmethylthio-κS)-1-phenylmethanimine-1-thiolato-κS]cobalt(III)(CAS DataBase Reference)
    10. NIST Chemistry Reference: chloro(η(5)-cyclopentadienyl)[N-(trimethylsilylmethylthio-κS)-1-phenylmethanimine-1-thiolato-κS]cobalt(III)(166772-09-4)
    11. EPA Substance Registry System: chloro(η(5)-cyclopentadienyl)[N-(trimethylsilylmethylthio-κS)-1-phenylmethanimine-1-thiolato-κS]cobalt(III)(166772-09-4)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 166772-09-4(Hazardous Substances Data)

166772-09-4 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 166772-09-4 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,6,6,7,7 and 2 respectively; the second part has 2 digits, 0 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 166772-09:
(8*1)+(7*6)+(6*6)+(5*7)+(4*7)+(3*2)+(2*0)+(1*9)=164
164 % 10 = 4
So 166772-09-4 is a valid CAS Registry Number.

166772-09-4Upstream product

166772-09-4Downstream Products

166772-09-4Relevant articles and documents

Addition of CHSiMe3 to the Co-S Bond of 1,2,5,3-cobaltadithiazole. Formation and reactions of stereoisomeric cobaltathiirane complexes

Mori, Yoshiko,Takehara, Masahiro,Sugiyama, Toru,Kajitani, Masatsugu,Akiyama, Takeo,et al.

, p. 81 - 88 (1995)

In the reaction between (η5-cyclopentadienyl)(1-phenylmethanimine-N,1-dithiolato)cobalt(III), , 1) and trimethylsilyldiazomethane, trimethylsilylmethylene adds between Co and S adjacent to N.Two geometrical isomers of cobaltathiirane complexes are formed: in the major addition product 2a, the trimethylsilyl group is located at the anti-position with respect to the cobaltadithiazole ring and in the minor product 2b, at the syn-position.These two stereoisomers are in equilibrium.Equilibrium is attained in 10 h at 80 deg C, when the reaction is started either from 2a or from 2b.Form the temperature dependence of the equilibrium, ΔG value of the isomerization of the stereoisomers is estimated to be 34 kJ mol-1.These isomeric trimethylsilylmethylene adducts react with HCl to give a common product, chloro(η5-cyclopentadienyl)cobalt(III) (4).By treatment with tetrabutylammonium fluoride, 4 undergoes a ring reforming reaction to give a methylene adduct, (η5-cyclopentadienyl)-1-phenylmethanimine-1-thiolato-κS>cobalt(III).Keywords: Cobalt; Thiirane; Cobaltadithiazole; Isomerization; Addition-elimination; Alkylidene

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