16682-30-7Relevant academic research and scientific papers
Transition-Metal-Free Synthesis of N-Arylphenothiazines through an N- And S-Arylation Sequence
Matsuzawa, Tsubasa,Hosoya, Takamitsu,Yoshida, Suguru
, p. 2347 - 2352 (2021/04/05)
An efficient synthetic method of N-arylphenothiazines from o-sulfanylanilines under transition-metal-free conditions is disclosed. An N- and S-arylation sequence of o-sulfanylanilines enabled us to synthesize a wide variety of N-arylphenothiazines. In par
Room temperature phosphorescence molecule based on phenothiazine derivative, preparation method and application thereof
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Paragraph 0033; 0034; 0035; 0036, (2019/01/24)
The invention discloses a room temperature phosphorescence molecule based on a phenothiazine derivative, a preparation method and application thereof. The room temperature phosphorescence molecule based on the phenothiazine derivative has a structure shown as formula (I), wherein R is -OCH3, -CH3, -H, -Br, -Cl, -F or -CF3. According to the invention, mainly phenothiazine is adopted as the core, and C-N coupling reaction is carried out to connect phenothiazine with a benzene ring derivative, and then oxidation is carried out to obtain the target product. The solid powder of the compounds all have room temperature phosphorescence phenomenon, and have a longest life up to 398ms, thus being applicable as anti-counterfeit materials. And the preparation method provided by the invention has the advantages of mild reaction conditions and high yield.
