166833-52-9

Upstream product

• 98-88-4 benzoyl chloride 
• 162212-46-6 (1R,6R,7R,8S)-7-hydroxy-8-methoxy-6-<(methoxymethoxy)methyl>-3-methyl-9-oxabicyclo<4.3.0>non-2-ene 
• 162212-38-6 (1R,3S,8R,9R)-8-(hydroxymethyl)-5-(methoxycarbonyl)-11,11-dimethyl-2,10,12-trioxatricyclo<7.3.0.0^3,8>dodec-4-ene 
• 162212-39-7 (1R,3R,8R,9R)-5-(methoxycarbonyl)-8-<(methoxymethoxy)methyl>-11,11-dimethyl-2,10,12-trioxatricyclo<7.3.0.0^3,8>dodec-4-ene 
• 162212-40-0 (1R,3R,8R,9R)-5-(hydroxymethyl)-8-<(methoxymethoxy)methyl>-11,11-dimethyl-2,10,12-trioxatricyclo<7.3.0.0^3,8>dodec-4-ene 
• 162212-41-1 (1R,3R,8R,9R)-5-(chloromethyl)-8-<(methoxymethoxy)methyl>-11,11-dimethyl-2,10,12-trioxatricyclo<7.3.0.0^3,8>dodec-4-ene 
• 162212-42-2 (1R,3R,8R,9R)-8-<(methoxymethoxy)methyl>-5,11,11-trimethyl-2,10,12-trioxatricyclo<7.3.0.0^3,8>dodec-4-ene 

Downstream Products

• 166833-54-1 Benzoic acid (3R,3aR,7aR)-3a-methoxymethoxymethyl-6-methyl-2-oxo-2,3,3a,4,5,7a-hexahydro-benzofuran-3-yl ester 
• 166833-53-0 Benzoic acid (2S,3R,3aR,7aR)-2-hydroxy-3a-methoxymethoxymethyl-6-methyl-2,3,3a,4,5,7a-hexahydro-benzofuran-3-yl ester 

Relevant academic research and scientific papers

Synthetic Studies on the Trichothecene Family from D-Glucose

Base-catalyzed intramolecular cyclization of D-glucose-derived substrate 10 provided a diastereomeric mixture of bicyclic β-hydroxyl diesters 6R and 6S.Further functionalization of the mixture afforded an enantiomerically pure bicyclic lactone 4.A double