16685-91-9

Basic information

• Product Name: 1,1-dichloro-3-ethoxy-2-fluoro-but-1-ene
• CAS NO: 16685-91-9
• Molecular Weight: 187.041
• Mol File: 16685-91-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,1-dichloro-3-ethoxy-2-fluoro-but-1-ene(CAS DataBase Reference)
• NIST Chemistry Reference: 1,1-dichloro-3-ethoxy-2-fluoro-but-1-ene(16685-91-9)
• EPA Substance Registry System: 1,1-dichloro-3-ethoxy-2-fluoro-but-1-ene(16685-91-9)

Safety Data

• Hazardous Substances Data: 16685-91-9(Hazardous Substances Data)

Upstream product

• 60-29-7 diethyl ether 
• 79-35-6 1,1'-dichloro-2,2'-difluoroethene 
• 6921-34-2 benzylmagnesium chloride 
• 75-16-1 methylmagnesium bromide 

Relevant articles and documents

Reaction of 1,1-Dichloro-2,2-difluoroethylene with Alkyl Grignard Reagents. Evidence for Radical Reaction Involving β-Hydrogen Atom Abstraction from Grignard Reagents. Implication Regarding the Mechanism of Reduction by Grignard Reagents

Reaction of CF2=CCl2 (1) with alkyl Grignard reagents (RMgX: R = CH3, C2H5, n-C3H7, i-C3H7, n-C4H9, s-C4H9, i-C4H9, t-C4H9, n-C8H17, C6H5CH2) in ether afforded complex mixtures containing RCF2CCl2H (3), RCF=CCl2, CH3CH2OCH(CH3)CF2CCl2H, and CH3CH2OCH(CH3)