166897-60-5Relevant academic research and scientific papers
Synthesis, Crystal Structure and Catalytic Activities of
Ko, Po-Hung,Chen, Tai-Yuen,Zhu, Jin,Cheng, Kin-Fai,Peng, Shie-Ming,Che, Chi-Ming
, p. 2215 - 2220 (1995)
The compound H2bbpc , which has good solubility in organic solvents, has been prepared.Reaction of with H2bbpc in ethanol and in the presence of triethylamine gave , the crystal structure of which has been determined.This complex is an active catalyst for alkene epoxidation by PhIO, cyclopropanation of styrene by ethyl diazoacetate and aziridination of styrene by PhINO2SC6H4Me-p.Its cyclic voltammogram in dichloromethane showed a reversible Ru(III)-Ru(II) couple at -0.55 V and an oxidation couple at 0.32 V.
