Synthesis, Crystal Structure and Catalytic Activities of

DOI: 10.1039/DT9950002215

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2215 - 2220 (1995)

Update date:2022-08-03

Topics:

Authors:

Ko, Po-Hung

Chen, Tai-Yuen

Zhu, Jin

Cheng, Kin-Fai

Peng, Shie-Ming

Che, Chi-Ming

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Article abstract of DOI:10.1039/DT9950002215

The compound H2bbpc <1,2-bis(tert-butylpyridine-2-carboxamido)-4,5-dichlorobenzene>, which has good solubility in organic solvents, has been prepared.Reaction of with H2bbpc in ethanol and in the presence of triethylamine gave , the crystal structure of which has been determined.This complex is an active catalyst for alkene epoxidation by PhIO, cyclopropanation of styrene by ethyl diazoacetate and aziridination of styrene by PhINO2SC6H4Me-p.Its cyclic voltammogram in dichloromethane showed a reversible Ru(III)-Ru(II) couple at -0.55 V and an oxidation couple at 0.32 V.

Full text of DOI:10.1039/DT9950002215

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