16695-39-9Relevant academic research and scientific papers
Selective heterogeneous palladium-catalyzed hydrogenations of watersoluble alkenes and alkynes
Tour, James M.,Pendalwar, Shekhar L.
, p. 4719 - 4722 (1990)
Treatment of water-soluble alkenes or alkynes with palladium(II) acetate and triethoxysilane at room temperature afforded the corresponding hydrogenated products in high yields. Simple introduction of a stoichiometric amount of hydrogen is accomplished by using triethoxysilane as the hydrogen source.
New Synthetic Methods, 12. - The Stereoselectivity of the Ramberg-Baecklund Rearrangement
Scholz, Dieter,Burtscher, Peter
, p. 517 - 521 (2007/10/02)
The influence of strong and weak bases in different solvents on the (E)/(Z) ratio of the Ramberg-Baecklund olefin synthesis of α-halosulfoncarboxylic acids in studied.With potassium tert-butoxide in dry dimethyl sulfoxide (E) ratios of more than 97 percent are achieved.With weak bases, such as 0.25 N sodium hydroxide, we found only equal amounts of (E) and (Z) olefins, apart from a few exceptions.
STEREOSPECIFIC SYNTHESIS OF PHEROMONES OF THE E-ALKENE SERIES FROM THE TELOMER OF BUTADIENE WITH PHENOL
Zakharkin, L. I.,Petrushkina, E. A.
, p. 1419 - 1422 (2007/10/02)
The stereospecific synthesis of 7E- and 9E-dodecenyl acetates, 7E- and 11E-tetradecenyl acetates, 11E-tetradecen-1-ol, and 11E-hexadecenyl acetate, i.e., E-olefinic sex pheromones, was realized from 1-phenoxy-2E,7-octadiene (the telomer of butadiene with phenol).
