166984-92-5Relevant academic research and scientific papers
Cyclopentaannulation of Allyl Alcohols via a Radical Cyclisation Reaction. Total Synthesis of 4-Epibakkenolide-A
Srikrishna, A.,Viswajanani, R.,Sattigeri, J. A.
, p. 469 - 470 (1995)
A four step cyclopentaannulation methodology starting from allyl alcohols using 5-exo-trig radical cyclisation as the key reaction, and its application to the total synthesis of 4-epibakkenolide is described.
A new tetrahodrofurannulation via tandem radical cyclisation reaction-reductive deoxygenation sequence
Srikrishna,Viswajanani,Yelamaggad
, p. 1127 - 1128 (1995)
Treatment of bromoketals 2, derived from allyl alcohols 1, with tributyltin chloride, sodium cyanoborohydride and AlBN furnished the tetrahydrofurannulated products 3 via a 5-exo-trig radical cyclisation reaction followed by reductive cleavage of ketal 4.
Tributyltin chloride-sodium cyanoborohydride mediated tandem radical cyclisation-reductive demethoxylation sequence
Srikrishna,Viswajanani,Yelamaggad
, p. 10479 - 10488 (2007/10/03)
Reaction of the bromoketals 3, 7a-g and 11 with tri-n-butyltin chloride and sodium cyanoborohydride in the presence of a catalytic amount of AIBN furnished the ethers 5, 8a-g and 13 via a tandem sequence comprising of a radical cyclisation reaction and tri-n-butylhalostannane and sodium cyanoborohydride mediated reductive demethoxylation of the resulting cyclic ketals.
