167010-81-3Relevant academic research and scientific papers
Fluorinated enol ethers bearing chiral arylsulphinyl groups
Bravo, Pierfrancesco,Bruche, Luca,Crucianelli, Marcello,Merli, Annamaria
, p. 127 - 130 (1995)
A synthesis of 2-alkoxy-2-fluoroalkyl-1-(p-tolylsulphinyl)ethenes 4 with good regioselectivity from γ-fluorosubstituted β-ketosulphoxides 3 is described - Keywords: Fluorinated enol ethers; Synthesis; Alkoxyfluoroalkyl(p-tolylsulphinyl)ethenes; NMR spectr
New fluorinated chiral synthons
Bravo,Farina,Frigerio,Meille,Viani,Soloshonok
, p. 987 - 1004 (2007/10/02)
The syntheses of new optically pure poly-halo and poly-fluoro oxiranes 5b-e by addition of diazomethane on the corresponding β-keto-γ-fluorosubstituted sulphoxide intermediates, both in keto 3, hydrate 4 or in keto/ hydrate form are described. Syntheses o
