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167024-66-0

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167024-66-0 Usage

General Description

Amino(4-bromophenyl)acetonitrile is a chemical compound with the molecular formula C8H7BrN2. It is an organic compound that contains a cyanide group, as indicated by the suffix "nitrile" in its name. The presence of the amino (NH2) group and the 4-bromophenyl substituent makes it a derivative of acetonitrile. amino(4-bromophenyl)acetonitrile is used as a building block in organic synthesis and pharmaceutical research. It can be utilized in the production of various types of pharmaceuticals and other organic compounds due to its chemical reactivity and functional groups. Amino(4-bromophenyl)acetonitrile is handled with caution as it can be toxic and may pose health risks if not properly managed.

Check Digit Verification of cas no

The CAS Registry Mumber 167024-66-0 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,6,7,0,2 and 4 respectively; the second part has 2 digits, 6 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 167024-66:
(8*1)+(7*6)+(6*7)+(5*0)+(4*2)+(3*4)+(2*6)+(1*6)=130
130 % 10 = 0
So 167024-66-0 is a valid CAS Registry Number.

167024-66-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 16, 2017

Revision Date: Aug 16, 2017

1.Identification

1.1 GHS Product identifier

Product name 2-amino-2-(4-bromophenyl)acetonitrile

1.2 Other means of identification

Product number -
Other names amino(4-bromophenyl)acetonitrile

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:167024-66-0 SDS

167024-66-0Relevant articles and documents

Facile Access to 1,4-Disubstituted Pyrrolo[1,2- a ]pyrazines from α-Aminoacetonitriles

Basha, Mushkin,Belema, Makonen,Dhar, T. G. Murali,Gupta, Anuradha,Gupta, Arun Kumar,Indasi, Gopi Kumar,Karmakar, Ananta,Mathur, Arvind,Meanwell, Nicholas A.,Ramalingam, Sridharan,Rampulla, Richard

supporting information, p. 441 - 449 (2020/01/23)

An efficient and practical synthetic protocol for the synthesis of 1,4-disubstituted pyrrolo[1,2- a ]pyrazine derivatives is described that originates from α-substituted pyrroloacetonitriles which, in turn, are readily available from aryl and alkyl aldehydes. The α-pyrroloacetonitriles were subjected to a Friedel-Crafts acylation with methyl chlorooxoacetate followed by reduction of the nitrile group under Pd-catalyzed hydrogenation conditions and finally aromatization with DDQ leading to the desired pyrrolo[1,2- a ]pyrazine derivatives. This method was generalized and successfully applied to various aryl, heteroaryl, and alkyl substrates. The developed protocol provides direct and convenient access to 1,4-disubstituted ring systems in moderate to good overall yields (51-68percent) without the need for purification of the intermediates. Further functionalization via the stepwise halogenation (bromination, iodination) and nitration was also demonstrated. In addition, the potential of the ester functionality for elaboration was demonstrated by manipulating into heterocyclic ring systems, exemplified by conversion into benzoxazole derivatives.

Gold-catalyzed oxidative couplings of two indoles with one aryldiazo cyanide under oxidant-free conditions

Singh, Rahulkumar Rajmani,Liu, Rai-Shung

supporting information, p. 4593 - 4596 (2017/04/28)

Gold-catalyzed oxidative couplings of two indoles and one α-cyano gold carbene to form bis(indolyl)methane derivatives are described. Two different indoles are compatible with these reactions to provide reasonable yields. A plausible mechanism is postulated to rationalize the experimental data including product distributions, D2O labeling, and the significant effects of gold catalysts and cyano groups.

An efficient and scalable synthesis of the spirocyclic glycine transporter inhibitor GSK2137305

Graham, Jonathan P.,Langlade, Nathalie,Northall, John M.,Roberts, Alastair J.,Whitehead, Andrew J.

experimental part, p. 44 - 48 (2011/09/15)

An efficient and scalable synthesis of a glycine transporter inhibitor is presented. The key steps in the synthetic sequence are the formation of a spirocyclic imidazolidinone from an -amino nitrile and a cyclic ketone and an arylation of 4-methyl imidazo

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