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167081-25-6 Usage


cis-4-(Boc-amino)cyclohexanol is used as a reagent to synthesize pyrazolo[3,4-d]pyrimidines, compounds that potentially act as anti-inflammatory and antitumor agents

Check Digit Verification of cas no

The CAS Registry Mumber 167081-25-6 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,6,7,0,8 and 1 respectively; the second part has 2 digits, 2 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 167081-25:
136 % 10 = 6
So 167081-25-6 is a valid CAS Registry Number.

167081-25-6 Well-known Company Product Price

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  • (Code)Product description
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  • Alfa Aesar

  • (H62238)  cis-4-(Boc-amino)cyclohexanol, 97%   

  • 167081-25-6

  • 250mg

  • 387.0CNY

  • Detail
  • Alfa Aesar

  • (H62238)  cis-4-(Boc-amino)cyclohexanol, 97%   

  • 167081-25-6

  • 1g

  • 1163.0CNY

  • Detail
  • Alfa Aesar

  • (H62238)  cis-4-(Boc-amino)cyclohexanol, 97%   

  • 167081-25-6

  • 5g

  • 4633.0CNY

  • Detail



According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 16, 2017

Revision Date: Aug 16, 2017


1.1 GHS Product identifier

Product name tert-Butyl cis-4-hydroxycyclohexylcarbamate

1.2 Other means of identification

Product number -
Other names cis-(4-Hydroxycyclohexyl)carbamic acid tert-butyl ester

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:167081-25-6 SDS

167081-25-6Relevant articles and documents

Compounds and methods of use


Page/Page column 496; 497, (2021/08/04)

Compounds are provided according to Formula (I): and pharmaceutically acceptable salts thereof, and pharmaceutical compositions thereof; wherein X1, X2, X3, X4, Y, A, L1, L2, R1, R2, R5, m and n are as defined herein. Compounds of the present invention are contemplated useful for the prevention and treatment of a variety of conditions.

Palladium-Catalyzed C-O Cross-Coupling as a Replacement for a Mitsunobu Reaction in the Development of an Androgen Receptor Antagonist

Hager, Anastasia,Guimond, Nicolas,Grunenberg, Lars,Hanisch, Christine,Steiger, Sebastian,Preuss, Andre

, p. 654 - 660 (2021/03/15)

A scalable and efficient synthesis of N-{trans-4-[(8-cyanoquinolin-4-yl)oxy]cyclohexyl}-3-fluorobenzamide (BAY 1161116), an androgen receptor antagonist, is reported. The original synthesis included a low-yielding Mitsunobu reaction and employed cis-aminocyclohexanol, which is accessible only via a troublesome synthesis, as a key building block. The novel synthetic pathway starts from readily available trans-aminocyclohexanol and features a palladium-catalyzed etherification reaction in place of the Mitsunobu reaction as the key step. This four-step synthesis can be performed reliably on a multikilogram scale, and purification of all intermediates as well as the final product can be achieved by simple extraction and crystallization procedures.

Catalytic Transfer Hydrogenation of Arenes and Heteroarenes

Gelis, Coralie,Heusler, Arne,Nairoukh, Zackaria,Glorius, Frank

supporting information, p. 14090 - 14094 (2020/10/19)

Transfer hydrogenation reactions are of great interest to reduce diverse molecules under mild reaction conditions. To date, this type of reaction has only been successfully applied to alkenes, alkynes and polarized unsaturated compounds such as ketones, imines, pyridines, etc. The reduction of benzene derivatives by transfer hydrogenation has never been described, which is likely due to the high energy barrier required to dearomatize these compounds. In this context, we have developed a catalytic transfer hydrogenation reaction for the reduction of benzene derivatives and heteroarenes to form complex 3-dimensional scaffolds bearing various functional groups at room temperature without needing compressed hydrogen gas.

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