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167110-07-8

Pt(O2CCF3)2(((CH3C6H4)2P)2CH2) is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 167110-07-8 Structure

  • Basic information

    1. Product Name: Pt(O2CCF3)2(((CH3C6H4)2P)2CH2)
    2. Synonyms:
    3. CAS NO:167110-07-8
    4. Molecular Formula:
    5. Molecular Weight: 861.617
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 167110-07-8.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: Pt(O2CCF3)2(((CH3C6H4)2P)2CH2)(CAS DataBase Reference)
    10. NIST Chemistry Reference: Pt(O2CCF3)2(((CH3C6H4)2P)2CH2)(167110-07-8)
    11. EPA Substance Registry System: Pt(O2CCF3)2(((CH3C6H4)2P)2CH2)(167110-07-8)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 167110-07-8(Hazardous Substances Data)

167110-07-8 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 167110-07-8 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,6,7,1,1 and 0 respectively; the second part has 2 digits, 0 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 167110-07:
(8*1)+(7*6)+(6*7)+(5*1)+(4*1)+(3*0)+(2*0)+(1*7)=108
108 % 10 = 8
So 167110-07-8 is a valid CAS Registry Number.

167110-07-8Upstream product

167110-07-8Relevant articles and documents

Steric effects in the chemistry of platinum cluster complexes

Hao, Leijun,Jobe, Ian R.,Vittal, Jagadese J.,Puddephatt, Richard J.

, p. 2781 - 2789 (1995)

A study of steric effects of the ligands R2PCH2PR2, R = aryl, on the formation and chemistry of the clusters [Pt3(μ3-CO)(μ-R2PCH2PR 2)3(O2CCF3)]+, 4, and [Pt3(μ3-CO)(μ-R2PCH2PR 2)3]2+, 8, is reported. When R = 2-MeC6H4, reduction of [Pt(O2CCF3)2(R2PCH 2PR2)] by CO/H2O gave only the binuclear complex [Pt2H(CO)(μ-R2PCH2PR2) 2]+, but with smaller groups R, further reduction to 4 (R = 4-MeC6H4, 3-MeC6H4, 3,5-Me2C6H3, 3,5-F2C6H3, 3,5-Cl2C6H3) or to [Pt4(μ-CO)2(μ-H)(μ-R2PCH2PR 2)3(R2PCH2PR2)] + (R = 4-MeC6H4, 3,5-F2C6H3) occurred. The complexes were characterized spectroscopically and for 4(CF3CO2), R = 3,5-Cl2C6H3, crystallographically [C80H42Cl24F6O5P 6Pt3·0.5CH2Cl 2·L5H2O, monoclinic, P21/n, a = 23.365(4) A, b = 24.599(4) A?, c = 19.141(7) A?, β = 102.44(2)°, Z = 4, R = 0.0727]. The complexes 8 can all form adducts with I-, SCN-, and CF3CO2- though evidence is presented that coordination of CF3CO2- is reversible in solution when R = 3,5-Cl2C6H3. Reactions of 8 with the ligands L = PPh3, PMePh2, P(OPh)3, and P(OMe)3 to form the adducts [Pt3(μ3-CO)(μ-R2PCH2PR 2)3L]2+ are reversible, and the position of equilibrium depends on the steric effects of R, indicating the steric sequence R = 4-MeC6H4, 3-MeC6H4 2C6H3 2C6H3 2C6H3.

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