80058-11-3Relevant articles and documents
Small bite-angle diphosphines - Synthesis and structure of low-valent complexes of bis(di-orthotolylphosphino)methane (dotpm) and related ligands
Filby, Maria,Deeming, Antony J.,Hogarth, Graeme,Lee, Mo-Yin
, p. 319 - 329 (2007/10/03)
The coordination chemistry of bis(di-ortho-tolylphosphino)methane (dotpm) has been studied. It is an excellent chelating ligand and a range of low-valent mononuclear complexes have been prepared; cis-[M(CO)4(η 2-dotpm)] (M = Cr, Mo,
SYNTHESIS AND PHYSICAL PROPERTIES OF CHLORODI(o-TOLYL)PHOSPHINE, LITHIUM DI(o-TOLYL)PHOSHIDE AND THE DIPHOSPHINE SERIES (o-TOLYL)2P(CH2)NP(o-TOYLYL) (n =1-4, 6,8)
Clark, Peter W.,Mulraney, Bernard J.
, p. 51 - 59 (2007/10/02)
The starting material chlorodi(o-tolyl)phosphine has been prepared by the reaction of phosphorus trichloride and the Grignard of o-chlorotoluene.The intermediate lithium di(o-tolyl)phosphide was obtained by the direct reaction of lithium metal and chlorod