167165-59-5Relevant academic research and scientific papers
The first chiral early-late heterobimetallic complex - A titanium(IV)-palladium(II) complex based on salenophos
Kless, Achim,Lefeber, Claudia,Spannenberg, Anke,Kempe, Rhett,Baumann, Wolfgang,Holz, Jens,Boerner, Armin
, p. 14599 - 14606 (2007/10/03)
The synthesis of the chiral polyfunctional diphosphine salenophos 1 is described. The new ligand bearing hard and soft coordination sites chelates titanium(IV) as well as palladium(II) in a defined manner provided a certain order during the introduction of the two metals was kept. In this way the first chiral early-late heterobimetallic complex could be synthesized. It was fully characterized by NMR spectroscopy and X-ray structural analysis. Remarkable features of the heterobimetallic complex are the trans coordination of the phosphine groups on palladium and the distance between Ti and Pd which is more than 4.13 A.
A new chiral multidentate ligand for asymmetric catalysis
Kless, Achim,Kadyrov, Renat,Boerner, Armin,Holz, Jens,Kagan, Henri B.
, p. 4601 - 4602 (2007/10/02)
The synthesis of enantiomerically pure (R,R)-N,N'-bis(3-diphenylphosphino-2-hydroxybenzylidene)-1,2-diphenyl- 1,2-ethanediamine (1) is described. This multidentate salentype ligand offers several possibilities for the construction of chiral mono-nuclear o
