167224-95-5Relevant academic research and scientific papers
Direct synthesis and properties of binuclear copper(II) complexes
Yang, Ruina,Wang, Dongmei,Kuang, Aiyan,Liu, Yingfan,Jin, Douman
, p. 1647 - 1662 (2001)
At room temperature, dibenzoyl peroxide undergoes an oxidative addition reaction with metallic copper powder and the relevant ligands afford binuclear copper(II) complexes, [Cu(OOCC6H5)2L]2, L = pyridine-2,6-dicarboxylic acid (L1), THF (L2), 3-aminopyridine (L3), 4-aminopyridine (L4), 2-methylpyridine (L5), 2,6-dimethylpyridine (L6) and 2-aminothiazol (L7). These complexes were further characterized by physico-chemical and spectroscopic methods. The structure of complex (7) has been determined by a single-crystal X-ray analysis. Each copper(II) ion is coordinated by two bridging bidentate benzoates and one L (as defined above) ligand to form dimeric binuclear molecules.
