16727-05-2

Basic information

• Product Name: 10-oxo-10-phenyl-decanoic acid methyl ester
• Synonyms: 10-oxo-10-phenyl-decanoic acid methyl ester
• CAS NO: 16727-05-2
• Molecular Weight: 276.376
• Mol File: 16727-05-2.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 10-oxo-10-phenyl-decanoic acid methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 10-oxo-10-phenyl-decanoic acid methyl ester(16727-05-2)
• EPA Substance Registry System: 10-oxo-10-phenyl-decanoic acid methyl ester(16727-05-2)

Safety Data

• Hazardous Substances Data: 16727-05-2(Hazardous Substances Data)

Upstream product

• 13735-81-4 1-styrenyloxytrimethylsilane 
• 2674-04-6 diphenyl cadmium 
• 14065-32-8 methyl 10-chloro-10-oxodecanoate 
• 71-43-2 benzene 

Downstream Products

• 6712-10-3 10-oxo-10-phenyldecanoic acid 
• 918895-49-5 8-(7-oxo-2-phenyl-9-trifluoromethyl-6,7-dihydro-3H-pyrrolo[3,2-f]quinolin-1-yl)-octanoic acid ethyl ester 

Relevant articles and documents

Photocatalytic decarboxylative alkylations mediated by triphenylphosphine and sodium iodide

Most photoredox catalysts in current use are precious metal complexes or synthetically elaborate organic dyes, the cost of which can impede their application for large-scale industrial processes. We found that a combination of triphenylphosphine and sodium iodide under 456-nanometer irradiation by blue light–emitting diodes can catalyze the alkylation of silyl enol ethers by decarboxylative coupling with redox-active esters in the absence of transition metals. Deaminative alkylation using Katritzky’s N-alkylpyridinium salts and trifluoromethylation using Togni’s reagent are also demonstrated. Moreover, the phosphine/iodide-based photoredox system catalyzes Minisci-type alkylation of N-heterocycles and can operate in tandem with chiral phosphoric acids to achieve high enantioselectivity in this reaction.

Photosensitive compound

Photosensitive compounds having preferably a functional group such as --SO2 Cl, --SO3 H, --SO3 R, STR1 (R, R', R" being alkyl) on a terminal benzene or naphthalene ring connected via a methylene group and STR2 moiety are improved in sensitivity to light and thermal stability, and thus useful in a photo resist.