2674-04-6

Basic information

• Product Name: Cadmium, diphenyl-
• CAS NO: 2674-04-6
• Molecular Formula: C12H10Cd
• Molecular Weight: 266.621
• Mol File: 2674-04-6.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Cadmium, diphenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Cadmium, diphenyl-(2674-04-6)
• EPA Substance Registry System: Cadmium, diphenyl-(2674-04-6)

Safety Data

• Hazardous Substances Data: 2674-04-6(Hazardous Substances Data)

Upstream product

• 587-85-9 diphenylmercury(II) 
• 100-58-3 phenylmagnesium bromide 
• 7790-80-9 cadmium(II) iodide 
• 555-54-4 diphenylmagnesium 
• 10108-64-2 cadmium(II) chloride 
• 7440-43-9 cadmium 

Downstream Products

• 6453-98-1 3-benzoylfuran 
• 6453-99-2 3-benzoylthiophene 
• 5650-07-7 3-methyl-1-phenyl-but-2-en-1-one 
• 98-80-6 phenylboronic acid 
• 101794-63-2 1-phenyl-hex-4t-en-1-one-(2,4-dinitro-phenylhydrazone) 
• 55563-72-9 3-methoxy-1-phenylpropan-1-one 
• 99853-91-5 4-chloro-1-phenyl-pent-3-en-1-one 
• 54487-71-7 3-benzoyl-1-methyl-indole-2-carboxylic acid 
• 4885-14-7 3-benzoyldurene 
• 33982-86-4 (2,3-dihydro-1H-inden-2-yl)(phenyl)methanone 
• 93-55-0 1-phenyl-propan-1-one 
• 6136-67-0 3-methoxybenzophenone 
• 55363-58-1 (3,4,5-trimethoxyphenyl)(phenyl)methanone 
• 93899-24-2 (4-hydroxy-3,5-dimethoxyphenyl)(phenyl)methanone 

Relevant articles and documents

Aryl C-N bond formation by electrophilic amination of diarylcadmium reagents with O-substituted ketoximes

Diorganocadmium reagents cannot react with ketoxime at room temperature. CuCN catalysis allows diarylcadmium reagents to react with ketoxime and to give corresponding arylamines in good to high yields at room temperature. According to the electronic effects of the substituent attached to the aromatic ring, functionalized diarylcadmium reagents show meta-para selectivity in their amination reactions. Also compared to diarylzinc reagents, diarylcadmium reagents react with O-substituted ketoxime under milder reaction conditions and they form corresponding arylamines in higher yields. CuCN cannot help dialkyl-, dicycloalky-, and dibenzylcadmium reagents to react with ketoxime. Our Aryl C-N bond formation method does not include cadmium excretion into the environment.