167300-31-4Relevant academic research and scientific papers
Alkyl radical cyclisations of methylenecyclopropane derivatives
Destabel, Christine,Kilburn, Jeremy D.,Knight, John
, p. 11267 - 11288 (2007/10/02)
Radical cyclisations of various methylenecyclopropane derivatives have been studied. Cyclisation of diphenylsubstituted (methylenecyclopropyl)butyl radical 10 gave the unexpected cyclohexene 5, via a series of radical rearrangements. In further studies, (
A Novel Sequence of Radical Rearrangements involving the 5-Exo Cyclisation of a 3-(Methylenecyclopropyl)propyl Radical
Destabel, Christine,Kilburn, Jeremy D.
, p. 596 - 598 (2007/10/02)
Radical 10, generated from the corresponding imidazolethiocarbonyl derivative 3 or the phenyl selenide 4, rearranges in a six-step process to give the cyclohexene 5, after reduction; this rearrangement sequence includes the selective 5-Exo cyclisation of
