167357-22-4

Basic information

• Product Name: N-<(S)-3-Hydroxy-3-phenylpropionyl>-(1S,5R,7R)-10,10-dimethyl-3-thioxo-2-aza-4-oxatricyclo<5.2.1.0^1,5>decane
• Synonyms: N-<(S)-3-Hydroxy-3-phenylpropionyl>-(1S,5R,7R)-10,10-dimethyl-3-thioxo-2-aza-4-oxatricyclo<5.2.1.0^1,5>decane
• CAS NO: 167357-22-4
• Molecular Weight: 345.463
• Mol File: 167357-22-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: N-<(S)-3-Hydroxy-3-phenylpropionyl>-(1S,5R,7R)-10,10-dimethyl-3-thioxo-2-aza-4-oxatricyclo<5.2.1.0^1,5>decane(CAS DataBase Reference)
• NIST Chemistry Reference: N-<(S)-3-Hydroxy-3-phenylpropionyl>-(1S,5R,7R)-10,10-dimethyl-3-thioxo-2-aza-4-oxatricyclo<5.2.1.0^1,5>decane(167357-22-4)
• EPA Substance Registry System: N-<(S)-3-Hydroxy-3-phenylpropionyl>-(1S,5R,7R)-10,10-dimethyl-3-thioxo-2-aza-4-oxatricyclo<5.2.1.0^1,5>decane(167357-22-4)

Safety Data

• Hazardous Substances Data: 167357-22-4(Hazardous Substances Data)

Upstream product

• 147168-90-9 (1S,5R,7R)-10,10-dimethyl-3-thioxo-2-aza-4-oxatricyclo<5.2.1.0^1,5>decane 
• 100-52-7 benzaldehyde 
• 167259-92-9 N-Acetyl-(1S,5R,7R)-10,10-Dimethyl-3-thioxo-2-aza-4-oxatricyclo<5.2.1.0^1,5>decane 

Downstream Products

• 36567-72-3 (S)-3-hydroxy-3-phenylpropanoic acid 

Relevant articles and documents

Asymmetric Aldol Type Reactions of Acetate Imide Enolates

Titanium-mediated chelation-controlled aldol type reactions of acetate thioimide with representative aldehydes proceed with high ?-facial differentiation.An investigation of the influence of the nature of the imide enolate ligands and the Lewis acids in t

An Unusual Enantioselective Aldol Type Reaction of Acetate Boryl Enolate Derived from Chiral Thioimide

The camphor-derived N-acetyloxazolidinethione has been used to effect enantioselective aldol type reactions of the derived 9-BBN enolate with a variety of aldehydes.Mechanistically, the observed facial selectivity is best explained by a boatlike transitio