167357-25-7

Basic information

• Product Name: N-<(S)-(E)-3-Hydroxy-5-(phenylthio)-4-pentenoyl>-(1S,5R,7R)-10,10-dimethyl-3-thioxo-2-aza-4-oxatricyclo<5.2.1.0^1,5>decane
• CAS NO: 167357-25-7
• Molecular Weight: 403.566
• Mol File: 167357-25-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: N-<(S)-(E)-3-Hydroxy-5-(phenylthio)-4-pentenoyl>-(1S,5R,7R)-10,10-dimethyl-3-thioxo-2-aza-4-oxatricyclo<5.2.1.0^1,5>decane(CAS DataBase Reference)
• NIST Chemistry Reference: N-<(S)-(E)-3-Hydroxy-5-(phenylthio)-4-pentenoyl>-(1S,5R,7R)-10,10-dimethyl-3-thioxo-2-aza-4-oxatricyclo<5.2.1.0^1,5>decane(167357-25-7)
• EPA Substance Registry System: N-<(S)-(E)-3-Hydroxy-5-(phenylthio)-4-pentenoyl>-(1S,5R,7R)-10,10-dimethyl-3-thioxo-2-aza-4-oxatricyclo<5.2.1.0^1,5>decane(167357-25-7)

Safety Data

• Hazardous Substances Data: 167357-25-7(Hazardous Substances Data)

Upstream product

• 147168-90-9 (1S,5R,7R)-10,10-dimethyl-3-thioxo-2-aza-4-oxatricyclo<5.2.1.0^1,5>decane 
• 80227-71-0 β-thiophenylacrolein 
• 167259-92-9 N-Acetyl-(1S,5R,7R)-10,10-Dimethyl-3-thioxo-2-aza-4-oxatricyclo<5.2.1.0^1,5>decane 

Relevant articles and documents

An Unusual Enantioselective Aldol Type Reaction of Acetate Boryl Enolate Derived from Chiral Thioimide

The camphor-derived N-acetyloxazolidinethione has been used to effect enantioselective aldol type reactions of the derived 9-BBN enolate with a variety of aldehydes.Mechanistically, the observed facial selectivity is best explained by a boatlike transitio