An Unusual Enantioselective Aldol Type Reaction of Acetate Boryl Enolate Derived from Chiral Thioimide

DOI: 10.1021/jo00105a040

Source and publish data:

Journal of Organic Chemistry p. 8187 - 8191 (1994)

Update date:2022-08-02

Topics: Enantioselective

Authors:

Yan, Tu-Hsin

Hung, An-Wei

Lee, Hui-Chun

Chang, Chii-Shin

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Article abstract of DOI:10.1021/jo00105a040

The camphor-derived N-acetyloxazolidinethione has been used to effect enantioselective aldol type reactions of the derived 9-BBN enolate with a variety of aldehydes.Mechanistically, the observed facial selectivity is best explained by a boatlike transitio

Full text of DOI:10.1021/jo00105a040

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