An Unusual Enantioselective Aldol Type Reaction of Acetate Boryl Enolate Derived from Chiral Thioimide

DOI: 10.1021/jo00105a040

Source and publish data:

Journal of Organic Chemistry p. 8187 - 8191 (1994)

Update date:2022-08-02

Topics: Enantioselective

Authors:

Yan, Tu-Hsin

Hung, An-Wei

Lee, Hui-Chun

Chang, Chii-Shin

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00105a040

The camphor-derived N-acetyloxazolidinethione has been used to effect enantioselective aldol type reactions of the derived 9-BBN enolate with a variety of aldehydes.Mechanistically, the observed facial selectivity is best explained by a boatlike transitio

Full text of DOI:10.1021/jo00105a040

Products guided by the article

Product name:N-<(S)-(E)-3-Hydroxy-5-(phenylthio)-4-pentenoyl>-(1S,5R,7R)-10,10-dimethyl-3-thioxo-2-aza-4-oxatricyclo<5.2.1.0^1,5>decane

Cas No:167357-25-7

R&D Labs maybe for 167357-25-7

Zibo Jujin Chemical Industry Co., Ltd.（Dongming Jujin Chemical Industry Co., Ltd. ）

Contact:+86-533-2975022

Address:No.99 Shanquan Road, Zhangdian District
Shanghai SMEC Trading Co., Ltd.

website:http://www.shanghaismec.com

Contact:+86-21-68811293

Address:ROOM 1101,NO.800 SHANGCHENG RD,SHANGHAI,CHINA
Shenzhen ZheYi Chemicals Co.,LTD(Shanghai Branch)

Contact:+86-21-54159691

Address:Room1002,Building No.2, Lane 98 Bixiu Road,Minhang District, Shanghai,China 201100
TIC Gums, Inc.

Contact:410-273-7300; 800-221-3953

Address:4609 Richlynn Dr., PO Box 369, Belcamp, MD, 21017-0369, USA
Nanjing Qirui Material Co., Ltd.

Contact:+86-25-52320053

Address:F4-5, #17 Building, Chuang Yi Yuan, No.6 Guanghua East Street, Nanjing, 210007 P.R.China

Relevant to this article

Studies on the Stereochemistry of Aplyronine A: Determination of the Stereochemistry of the C21-C34 Fragment

Doi:10.1016/S0040-4039(00)61370-9
(1993)
Pyrrolylquinoxalinediones: A new class of AMPA receptor antagonists

Doi:10.1016/S0960-894X(96)00534-3
(1996)
Synthesis and cytotoxicity of novel γ-piperidone-containing dibenzo-1,7-diaza-14-crown-4 ethers

Doi:10.1016/j.mencom.2019.07.004
(2019)
Studies related to the carbohydrate sectors of esperamicin and calicheamicin: Definition of the stability limits of the esperamicin domain and fashioning of a glycosyl donor from the calicheamicin domain

Doi:10.1021/ja00126a013
(1995)
Nonpeptide arginine vasopressin antagonists for both V(1A) and V₂ receptors: Synthesis and pharmacological properties of 4'-(1,4,5,6- tetrahydroimidazo[4,5-d][1]benzoazepine-6-carbonyl)benzanilide derivatives and 4'-(5,6-dihydro-4H-thiazolo[5,4-d] [1]benzoazepine-6-carbonyl)benzanilide derivatives

Doi:10.1248/cpb.48.21
(2000)
Doi:10.1007/BF00481612
()

Article Doi