16749-13-6

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InChI:InChI=1/H5P/h1H5

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Synthesis of inulin derivatives with quaternary Phosphonium (cas 16749-13-6) salts and their antifungal activity07/23/2019

Inulin is a kind of renewable and biodegradable carbohydrate with good water solubility and numerous physiological functions. For further utilization of inulin, chemical modification can be applied to improve its bioactivities. In this paper, five novel inulin derivatives were synthesized via ch...detailed

Methoxy-phenyl groups reduce the cytotoxicity and increase the aqueous solubility of Phosphonium (cas 16749-13-6) zwitterions and salts07/22/2019

The ability of phosphonium cations to act as intracellular transport vectors is well-established. Previous research has demonstrated that phosphonioalkylthiosulfate zwitterions, and ω-thioacetylalkylphosphonium salts are useful precursors for the formation of phosphonium-functionalised gold nan...detailed

Synthesis and reactivity of [M(η3-allyl)(η2-amidinato)(CO)2(Phosphonium (cas 16749-13-6) ylide)] (M = Mo, W): Investigation of the ligand properties of Phosphonium (cas 16749-13-6) ylides07/20/2019

Phosphonium ylide complexes of Mo and W formulated as [M(η3-allyl){η2-(NPh)2CH}(CO)2(CH2PR3)] (M = Mo, R = Me: 2a-Mo; M = Mo, R = Ph: 2b-Mo, and M = W, R = Me: 2a-W) were prepared by the reaction of amidinato(pyridine) complex, [M(η3-allyl){η2-(NPh)2CH}(CO)2(NC5H5)] (M = Mo: 1-Mo and M = W: ...detailed

Reductive silylation of gem-difluorinated Phosphonium (cas 16749-13-6) salts07/21/2019

gem-Difluorinated phosphonium salts, generated from aldehydes and difluorinated phosphobetaine reagent, were converted into corresponding silicon reagents. The reductive silylation of carbon-phosphorus bond is carried out using a combination of magnesium and chlorotrimethylsilane in dimethylform...detailed

Tumor cell uptake and selectivity of gadolinium(III)-Phosphonium (cas 16749-13-6) complexes: The role of delocalisation at the Phosphonium (cas 16749-13-6) centre07/19/2019

The synthesis of a series of bifunctional Gd(III) complexes 1–3 covalently bound to arylphosphonium cations possessing a varying degree of delocalisation at the phosphonium centre is presented. The influence of the degree of delocalisation was investigated with regards to in vitro cytotoxicity,...detailed

Biocidal activity of ROMP- polymer coatings containing quaternary Phosphonium (cas 16749-13-6) groups07/18/2019

Bacterial surface contamination is considered as one of the main causes of secondary infection. Herein, cationic polymers containing alkyl or aromatic quaternary phosphonium groups were synthesized via ring opening metathesis polymerization (ROMP) and successfully deposited onto a glass surface ...detailed