167563-91-9Relevant academic research and scientific papers
Cascade Radical Cyclization-Fragmentation-Transannular-Ring Expansion Reactions Involving Oximes. A New Approach to the Synthesis of Angular Triquinanes
Hollingworth, Gregory J.,Pattenden, Gerald,Schulz, Darren J.
, p. 381 - 400 (2007/10/02)
Treatment of the acetylene-substituted cyclobutanone oxime ether (13) with (Me3Si)3SiH leads, in one pot, to the 5,6-bicyclic enone oxime (14) in 70percent yield.It is suggested that the formation of (14) from (13) proceeds by way of a novel double ring e
Cascade radical reactions in synthesis. A new radical mediated double ring expansion-cyclisation process oxime ethers
Pattenden,Schultz
, p. 6787 - 6790 (2007/10/02)
Treatment of the acetylene substituted cyclobutanone oxime ether (1) with (Me3Si)3SiH leads, in one pot, to the bicycle (2, 70%) by way of a novel double ring expansion-cyclisation process involving aminyl radical intermediates.
