154039-06-2

Upstream product

• 154039-05-1 4-(2'-t-butyldimethylsilylethynyl)-7-(t-butyldimethylsilyloxy)hept-1-ene 
• 154039-04-0 1-(t-butyldimethylsilyl)-6-(t-butyldimethylsilyloxy)hex-1-yne 
• 167564-10-5 4-(2'-t-butyldimethylsilylethynyl)hept-6-en-1-ol 
• 14633-54-6 cyclopropylphenylsulfide 
• 154039-03-9 4-(2'-t-butyldimethylsilylethynyl)hept-6-enal 

Downstream Products

• 167563-91-9 2-{3-[(tert-Butyl-dimethyl-silanyl)-ethynyl]-hex-5-enyl}-cyclobutanone O-benzyl-oxime 
• 154039-08-4 2-(3'-ethynylhex-5'-enyl)cyclobutanone O-benzyloxime 

Relevant academic research and scientific papers

Cascade radical reactions in synthesis. A new radical mediated double ring expansion-cyclisation process oxime ethers

Treatment of the acetylene substituted cyclobutanone oxime ether (1) with (Me3Si)3SiH leads, in one pot, to the bicycle (2, 70%) by way of a novel double ring expansion-cyclisation process involving aminyl radical intermediates.

Cascade Radical Cyclization-Fragmentation-Transannular-Ring Expansion Reactions Involving Oximes. A New Approach to the Synthesis of Angular Triquinanes

Treatment of the acetylene-substituted cyclobutanone oxime ether (13) with (Me3Si)3SiH leads, in one pot, to the 5,6-bicyclic enone oxime (14) in 70percent yield.It is suggested that the formation of (14) from (13) proceeds by way of a novel double ring e