167641-74-9

Upstream product

• 100-52-7 benzaldehyde 
• 39753-76-9 3-hydroxyamino-3-methyl-butan-2-one 

Downstream Products

• 593286-07-8 4,4,5-trimethyl-2-phenyl-4H-imidazole 3-oxide 
• 127832-39-7 4-Hydroximino-5,5-dimethyl-4-oxo-2-phenyl-1-pyrroline-1-oxide 
• 593286-20-5 2-[(2-hydroxyethyl)(4,4-dimethyl-2-phenyl-3-oxido-4H-imidazol-5-yl)amino]ethanol 
• 593286-19-2 1-(4,4-dimethyl-2-phenyl-3-oxido-4H-imidazol-5-yl)piperidine 
• 593286-18-1 N,N,4,4-tetramethyl-2-phenyl-4H-imidazol-5-amine 3-oxide 
• 593286-14-7 4,4-dimethyl-2-phenyl-4H-imidazole-5-carbonitrile 3-oxide 

Relevant academic research and scientific papers

Synthesis and oxidation of 1-hydroxy-3(2)-imidazoline-derived enaminones

Interaction of 1-hydroxy-3-imidazoline and 3-imidazoline 3-oxide derivatives with esters in the presence of LDA gives enaminones, derivatives of imidazolidine. Oxidation of these compounds with MnO2 leads to 4H-imidazole N-oxides, oxidative dimerization products, or stable nitroxyl radicals, depending on the structure of the initial compound.

Grignard reagent addition to 5-alkylamino-4H-imidazole 3-oxides: Synthesis of new pH-sensitive spin probes

4,4-Dimethyl-4H-imidazole-5-carbaldehyde oxime 3-oxides 4 were prepared by oxidation and nitrosation of 4,5,5-trimethyl-2,5-dihydro-1H-imidazol-1-ols. The oximes 4 were converted to 5-cyano derivatives; the latter react with primary or secondary amines to