167750-63-2Relevant academic research and scientific papers
Diastereoselective Synthesis of α-Hydroxy- and α-Aminoindolizidines and -quinolizidines. Evidence for a Novel Cyclization/Hydride Migration Mechanism in the TiCl4-Induced Reaction of Prolinal Benzylimines by Deuterium Labelling Studies
Laschat, Sabine,Grehl, Matthias
, p. 2023 - 2034 (2007/10/02)
Lewis acid-catalyzed of prolinal and 2-piperidinecarbaldehyde benzylimines 11, 12 results in the diastereoselective formation of α-amino-β-alkyl-substituted indolizidines 15, 17, 19, 21 and -quinolizidines 16, 18, 20, respectively.Both diastereoselectivit
