167774-23-4Relevant articles and documents
Crossing the Boundaries between Marine and Muguet: Discovery of Unusual Lily-of-the-Valley Odorants Devoid of Aldehyde Functions
Jordi, Samuel,Kraft, Philip
, (2018/06/04)
Since 6-isopropyl- (11) and 6-isobutyl-2H-benzo[b][1,4]dioxepin-3(4H)-one (12) instead of the expected marine odor had been reported to possess lily-of-the-valley notes, albeit weaker than benchmark odorants, the influence of a cyclopropyl ring instead of
Synthesis of [2-(methoxyaryl)-1-methylethyl]phosphinic acids from red phosphorus and (allyl)(methoxy)benzenes
Malysheva,Kuimov,Artem'Ev,Belogorlova,Albanov,Gusarova,Trofimov
, p. 1787 - 1791 (2013/11/19)
(Allyl)(methoxy)benzenes react with red phosphorus in the superbasic system KOH-DMSO in the presence of small amounts of water and hydroquinone (3 h, 130 C) to regio- and chemoselectively give [2-(methoxyaryl)-1-methylethyl]phosphinic acids in preparative yields up to 52%. The reactions involve isomerization of allylbenzenes into (prop-1-enyl)benzenes.