29283-76-9

Upstream product

• 60-29-7 diethyl ether 
• 590-15-8 trans-2-propenyl bromide 
• 1522-03-8 tetra-cis-propenyl stannane 
• 591-51-5 phenyllithium 
• 1522-03-8 tetra-trans-propenyl stannane 

Downstream Products

• 6052-56-8 1,1-diphenyl-2-buten-1-ol 
• 52755-38-1 (Z)-1-phenyl-but-2-en-1-ol 
• 19140-58-0 1,2,3,4,5-pentafluoro-6-(prop-1-en-1-yl)benzene 
• 1554-48-9 1,2,4,5-Tetrafluor-3.6-bis--benzol 
• 1554-48-9 1,2,4,5-Tetrafluor-3--6--benzol 
• 130516-13-1 diphenylmethyl (6R,7S)-7-(phenoxyacetamido)-3-<(Z)-1-propenyl>ceph-3-em-4-carboxylate 
• 92757-22-7 (Z)-(S)-1-Cyclohexyl-1-hydroxy-pent-3-en-2-one 
• 5194-51-4 (2E,4E)-hexa-2,4-diene 
• 5194-50-3 (E,Z)-2,4-hexadiene 
• 6108-61-8 cis,cis-2,4-Hexadien 
• 52922-19-7 erythro-2-methyl-1-phenyl-3-buten-1-ol 
• 52922-10-8 2-methyl-1-phenyl-3-buten-1-ol 
• 169129-36-6 methyl (Z)-3-<2-ethyl>-4-hexenoate 
• 404001-70-3 (1R,2S,5S)-5-Methyl-2-((Z)-propenyl)-6-oxa-bicyclo[3.1.0]hexan-2-ol 

Relevant academic research and scientific papers

Ligand-Free Iron-Catalyzed Carbon(sp2)-Carbon(sp2) Cross-Coupling of Alkenyllithium with Vinyl Halides

An efficient ligand-free iron-catalyzed cross-coupling reaction involving alkenyllithium and vinyl iodides was developed to form diene species in moderate to good yields. This new iron-catalyzed cross-coupling reaction provides a mild, inexpensive, and environmentally friendly avenue toward synthesis of diversified diene derivatives.

Palladium-Catalyzed [3+3] Annulation of Vinyl Chromium(0) Carbene Complexes through Carbene Migratory Insertion/Tsuji–Trost Reaction

Vinyl chromium(0) Fischer carbene complexes were employed as the source of π-allylic palladium species for catalytic [3+3] annulation under palladium catalysis. Mechanistically, this transformation is proposed to involve carbene migratory insertion and intramolecular Tsuji–Trost reaction as the key steps. Substituted six-membered heterocyclic flavonones and quinolines are obtained, depending on the nucleophilic functional group on the coupling partners.