167897-42-9

Basic information

• Product Name: N,N-bis((6-phenyl-2-pyridyl)methyl)-N-((2-pyridyl)-methyl)amine
• Synonyms: N,N-bis((6-phenyl-2-pyridyl)methyl)-N-((2-pyridyl)-methyl)amine
• CAS NO: 167897-42-9
• Molecular Weight: 442.563
• Mol File: 167897-42-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N,N-bis((6-phenyl-2-pyridyl)methyl)-N-((2-pyridyl)-methyl)amine(CAS DataBase Reference)
• NIST Chemistry Reference: N,N-bis((6-phenyl-2-pyridyl)methyl)-N-((2-pyridyl)-methyl)amine(167897-42-9)
• EPA Substance Registry System: N,N-bis((6-phenyl-2-pyridyl)methyl)-N-((2-pyridyl)-methyl)amine(167897-42-9)

Safety Data

• Hazardous Substances Data: 167897-42-9(Hazardous Substances Data)

Downstream Products

• 628291-85-0 [(N,N-bis((6-phenyl-2-pyridyl)methyl-N-((2-pyridyl)methyl)amine)Zn(ONHC(O)CH₃)](ClO₄) 
• 872993-24-3 acetylacetonato(N,N-bis((6-phenyl-2-pyridyl)methyl)-N-((2-pyridyl)methyl)amine)nickel(II) perchlorate 
• 872993-25-4 [(N,N-bis((6-phenyl-2-pyridyl)methyl)-N-((2-pyridyl)methyl)amine)Ni(H₂O)(benzoato)2] 
• 1338660-82-4 [(6-Ph₂TPA)Co(PhCO₂)]ClO₄ 
• 932703-85-0 [(6-Ph₂TPA)Ni(O₂CPh)]ClO₄ 
• 1202525-28-7 [(N,N-bis((6-phenyl-2-pyridyl)methyl)-N-((2-pyridyl)methyl)amine)Zn(II)(3-hydroxyflavonolate)](triflate) 
• 1202525-22-1 [(N,N-bis((6-phenyl-2-pyridyl)methyl)-N-((2-pyridyl)methyl)amine)Co(II)(3-hydroxyflavonolate)](triflate) 

Relevant articles and documents

Halide-promoted dioxygenolysis of a carbon-carbon bond by a copper(II) diketonate complex

A mononuclear Cu(II) chlorodiketonate complex was prepared, characterized, and found to undergo oxidative aliphatic carbon-carbon bond cleavage within the diketonate unit upon exposure to O2 at ambient temperature. Mechanistic studies provide evidence for a dioxygenase-type C-C bond cleavage reaction pathway involving trione and hypochlorite intermediates. Significantly, the presence of a catalytic amount of chloride ion accelerates the oxygen activation step via the formation of a Cu-Cl species, which facilitates monodentate diketonate formation and lowers the barrier for O2 activation. The observed reactivity and chloride catalysis is relevant to Cu(II) halide-catalyzed reactions in which diketonates are oxidatively cleaved using O2 as the terminal oxidant. The results of this study suggest that anion coordination can play a significant role in influencing copper-mediated oxygen activation in such systems.