N,N-bis((6-phenyl-2-pyridyl)methyl)-N-((2-pyridyl)-methyl)amine

Base Information

• Chemical Name: N,N-bis((6-phenyl-2-pyridyl)methyl)-N-((2-pyridyl)-methyl)amine
• CAS No.: 167897-42-9
• Molecular Formula: C₃₀H₂₆N₄
• Molecular Weight: 442.563
• Mol file: 167897-42-9.mol

Synonyms:N,N-bis((6-phenyl-2-pyridyl)methyl)-N-((2-pyridyl)-methyl)amine

Chemical Property of N,N-bis((6-phenyl-2-pyridyl)methyl)-N-((2-pyridyl)-methyl)amine

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of N,N-bis((6-phenyl-2-pyridyl)methyl)-N-((2-pyridyl)-methyl)amine

There total 1 articles about N,N-bis((6-phenyl-2-pyridyl)methyl)-N-((2-pyridyl)-methyl)amine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[(N,N-bis((6-phenyl-2-pyridyl)methyl)-N-((2-pyridyl)methyl)amine)Cu(PhC(O)CClC(O)Ph)]ClO4 → N,N-bis((6-phenyl-2-pyridyl)methyl)-N-((2-pyridyl)-methyl)amine (167897-42-9)

Guidance literature:

[(N,N-bis((6-phenyl-2-pyridyl)methyl)-N-((2-pyridyl)methyl)amine)Cu(PhC(O)CClC(O)Ph)]ClO₄; With water; oxygen; In acetonitrile; at 25 ℃; for 2.5h; Inert atmosphere; Sealed tube;

With ammonium hydroxide; In dichloromethane;

DOI:10.1021/ja502577b

Reference yield: 98.0%

3-hydroxyflavone (577-85-5,66585-05-5) + N,N-bis((6-phenyl-2-pyridyl)methyl)-N-((2-pyridyl)-methyl)amine (167897-42-9) + zinc trifluoromethanesulfonate (54010-75-2) → [(N,N-bis((6-phenyl-2-pyridyl)methyl)-N-((2-pyridyl)methyl)amine)Zn(II)(3-hydroxyflavonolate)](triflate) (1202525-28-7)

Guidance literature:

With tetramethylammonium hydroxide pentahydrate; In methanol; byproducts: (Me4N)(SO3CF3); under N2; MeOH soln. of Zn salt added to solid amine; stirred until the amine dissolved; added to MeOH soln. contg. 3-hydroxyflavonol and Me4NOH*5H2O; stirred at ambient temp. overnight; solvent removed under reduced pressure; suspended on top of Celite plug;washed (distd. H2O); dissolved in CH2Cl2; filtrate collected; brought t o dryness under reduced pressure; dissolved in CH2Cl2; Et2O added; cooled (-30.degrede.C, 12 h); elem. anal.;

DOI:10.1021/ic901405h

Reference yield: 96.0%

nickel(II) perchlorate hexahydrate + N,N-bis((6-phenyl-2-pyridyl)methyl)-N-((2-pyridyl)-methyl)amine (167897-42-9) + 1,3-diphenylpropanedione (120-46-7,61346-73-4) → (dibenzoylmethane(-1H))(N,N-bis((6-phenyl-2-pyridyl)methyl)-N-((2-pyridyl)methyl)amine)nickel(II) perchlorate

Guidance literature:

With Me₄NOH*5H₂O; In acetonitrile; byproducts: MeNClO4; MeCN soln. of Ni salt added to soln. of ligand (molar ratio 1:1) in MeCN; stirred at ambient temp. for ca. 15 min; PhC(O)CH2C(O)Ph (1 equiv.) added; Me4NOH*5H2O added; stirred at ambient temp. for 15-20 h in air; solvent removed under reduced pressure; dissolved in CH2Cl2; filtered through Celite-glass wool plug; filtrate brought to dryness under reduced pressure; recrystd. by Et2O diffusion into MeCN-MeOH soln. at ambient temp.; elem. anal.;

DOI:10.1021/ic061177i

Downstream raw materials:

[(N,N-bis((6-phenyl-2-pyridyl)methyl-N-((2-pyridyl)methyl)amine)Co(ONHC(O)CH₃)](ClO₄)

[(N,N-bis((6-phenyl-2-pyridyl)methyl-N-((2-pyridyl)methyl)amine)Zn(ONHC(O)CH₃)](ClO₄)

Ni((N,N-bis((6-phenyl-2-pyridyl)methyl)-N-((2-pyridyl)methyl)amine)(MeCN)Cl(ClO₄)

acetylacetonato(N,N-bis((6-phenyl-2-pyridyl)methyl)-N-((2-pyridyl)methyl)amine)nickel(II) perchlorate