167904-07-6Relevant articles and documents
Direct one-pot highly enantioselective assembly of polyketide and carbohydrate synthons
Zhao, Gui-Ling,Liao, Wei-Wei,Córdova, Armando
, p. 4929 - 4932 (2007/10/03)
A short, direct, catalytic, enantioselective synthesis of polyketide segments and carbohydrates is presented. The novel, direct, one-pot, organocatalytic asymmetric tandem cross-aldol/Horner-Wittig-Emmons reactions assemble polyketide and carbohydrate der
Intramolecular Tishchenko reactions of protected hexos-5-uloses: A novel and efficient synthesis of L-idose and L-altrose
Adinolfi,Barone,De Lorenzo,Iadonisi
, p. 336 - 338 (2007/10/03)
Protected t-butyl esters of aldonic acids with the rare L-ido and L- altro configuration can be effectively obtained by a diastereoselective Tishchenko reaction of hexos-5-uloses induced by t-BuOSmI2. These compounds can be easily converted int