167955-25-1

Basic information

• Product Name: Methyl phenylpyrophosphonate
• CAS NO: 167955-25-1
• Molecular Weight: 326.226
• Mol File: 167955-25-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Methyl phenylpyrophosphonate(CAS DataBase Reference)
• NIST Chemistry Reference: Methyl phenylpyrophosphonate(167955-25-1)
• EPA Substance Registry System: Methyl phenylpyrophosphonate(167955-25-1)

Safety Data

• Hazardous Substances Data: 167955-25-1(Hazardous Substances Data)

Upstream product

• 10088-45-6 methyl phenylphosphonic acid 
• 121-70-0 phenylphosphonous acid 

Downstream Products

• 2240-41-7 dimethyl phenylphosphonate 

Relevant articles and documents

(1H-Benzotriazol-1-yloxy)tris(dimethylamino)phosphonium Hexafluorophosphate- and (1H-Benzotriazol-1-yloxy)tripyrrolidinophosphonium Hexafluorophosphate-Mediated Activation of Monophosphonate Esters: Synthesis of Mixed Phosphonate Diesters, the Reactivity of the Benzotriazolyl Phosphon...

A general method for synthesizing mixed phosphonate diesters from monoesters using (1H-benzotriazol-1-yloxy)tris(dimethylamino)phosphonium hexafluorophosphate or (1H-benzotriazol-1-yloxy)tripyrrolidinophosphonium hexafluorophosphate reagents is described.The reaction proceeded through a benzotriazolyl ester as shown by comparison with other reagents such as DCC, DCC/DMAP, DCC/1-hydroxybenzotriazole, bromotris(dimethylamino)phosphonium hexafluorophosphate, or O-(1H-benzotriazol-1-yl)-N,N,N',N'-tetramethyluronium hexafluorophosphate and by 31P NMR analysis.This benzotriazolyl phosphonic ester intermediate was more reactive toward alcohols than toward amines, contrary to its carboxylic analogue.