167971-41-7Relevant academic research and scientific papers
Alkyne migration in alkylidene carbenoid species: A new method of polyyne synthesis
Eisler, Sara,Chahal, Navjot,McDonald, Robert,Tykwinski, Rik R.
, p. 2542 - 2550 (2007/10/03)
The synthesis of conjugated polyyne structures via a modification of the Fritsch-Buttenberg-Wiechell (FBW) rearrangement is reported. Our adaptation provides for the 1,2-migration of an alkyne in a carbene/carbenoid intermediate that is conveniently effec
2. Tetraethynylethenes: Fully Cross-Conjugated ?-Electron Chromophores and Molecular Scaffolds for All-Carbon Networks and Carbon-Rich Nanomaterials
Anthony, John,Boldi Armen M.,Rubin, Ives,Hobi, Markus,Gramlich, Volker,et al.
, p. 13 - 45 (2007/10/02)
The preparation of tetraethynylethene (3,4-diethynylhex-3-ene-1,5-diyne) 1 as well as of a great diversity of differentially mono-, di-, and triprotected derivatives by newly developed synthetic routes is described.These fully cross-conjugated molecules a
