16802-11-2Relevant articles and documents
Total Synthesis of (±)-Patriscabrol and (±)-Boschnialactone
Chiu, Jiun-Yuh,Chiu, Chih-Tsao,Chang, Nein-Chen
, p. 59 - 63 (1997)
A total synthesis of (±)-patriscabrol (1) and (±)-boschnialactone (2) is described. The cyclopentapyranone skeleton is assembled by means of Baeyer-Villiger oxidation of ketol 5.
Formal synthesis of (±)-hop ether, (±)-isoboonein, and (±)-iridomyrmecin
Chang, Meng-Yang,Hsu, Ru-Ting,Lin, Chun-Yu,Chen, Bor-Fong,Lin, Shiang-Tsern,Chang, Nein-Chen
, p. 271 - 282 (2007/10/03)
A general synthesis of (±)-hop ether (5), (±)-isoboonein (6), and (±)-iridomyrmecin (7) from bicyclo[2.2.1]ketone (9) is described. Cyclopentenoid aldehyde (10) and bicyclo[3.2.1]lactone (11) are the key intermediates.
Total synthesis of (±)-boschnialactone and (±)-tetrahydroanhydrodesoxyaucubigenin
Chang, Meng-Yang,Lin, Ching-Han,Lee, An-Yang,Tai, Huo-Mu,Chang, Nein-Chen
, p. 205 - 210 (2007/10/03)
A total synthesis of (±)-boschnialactone (1) and (±)-tertahydroanhydrodesoxyaucubigenin (2) is described and trisubstitued cyclopentenoid 3 is a key intermediate.