168103-01-3Relevant academic research and scientific papers
Total Synthesis, Configuration Assignment, and Cytotoxic Activity Evaluation of Protulactone A
Markovi?, Martin,Koó?, Peter,?arny, Tomá?,Sokoliová, Saskia,Bohá?iková, Nikola,Moncol′, Ján,Gracza, Tibor
, p. 1631 - 1638 (2017/05/31)
The first total synthesis and absolute configuration assignment of protulactone A (1) has been achieved. Four stereoisomers, 1a, ent-1a, 1b, and ent-1b, of this natural polyketide were prepared by chiral pool synthesis starting from l- and d-arabinose, re
Synthesis of tri- and tetrasaccharide glycosides of (4S)-4-hydroxy-d-proline relevant to the cell wall O-glycans of green alga Chlamydomonas reinhardtii
Zhu, Kai,Yang, Jin-Song
, p. 3113 - 3123 (2016/05/19)
The synthesis of tri- and tetrasaccharide glycosides of (4S)-4-hydroxy-d-proline 1 and 2 with unusual glycan motifs has been achieved efficiently. The assembly of the synthetically challenging 1,2-cis linked arabino- and galactofuranoside frameworks withi
Convenient conversion of wheat hemicelluloses pentoses (d-xylose and l-arabinose) into a common intermediate
Bercier, Ariane,Plantier-Royon, Richard,Portella, Charles
, p. 2450 - 2455 (2008/02/12)
The transformation of d-xylose and l-arabinose, the two major components of wheat straw and bran, into a unique multifunctional, optically pure, five-carbon synthon has been achieved. The synthetic sequence requires three steps: suitable protection of the
Synthesis and RNA-selective hybridization of α-L-ribo- and β-D-lyxo-configured oligonucleotides
Gaubert, Gilles,Ravindra Babu,Vogel, Stefan,Bryld, Torsten,Vester, Birte,Wengel, Jesper
, p. 2278 - 2294 (2007/10/03)
Three α-l-ribofuranosyl analogues of RNA nucleotides (α-l-RNA analogues) have been synthesized and incorporated into oligonucleotides using the phosphoramide approach on an automated DNA synthesizer. The 4′-C-hydroxymethyl-α-l-ribofuranosyl thymine monome
The Raction of Acetyliron 5-C5H5)Fe(CO)(PPh3)(COCH3)> with Sugar Aldehydes. New Synthesis of Deoxysugars
Pakulski, Zbigniew,Zamojski, Aleksander
, p. 871 - 908 (2007/10/02)
Aldol reactions of sugar aldehydes (5-13) with enolate 2 of racemic and both enantiomeric forms of acetyliron were investigated.The steric course of reactions depended strongly on the counterions used.High stereocontrol was achieved with the following cat
