168132-19-2Relevant academic research and scientific papers
Enantioselective total synthesis and absolute configuration of the natural norsesquiterpene 7-demethyl-2-methoxycalamenene by a silane-terminated intramolecular heck reaction
Tietze, Lutz F.,Raschke, Thomas
, p. 1981 - 1987 (2007/10/03)
The total synthesis of the norsesquiterpene 7-demethyl-2-methoxycalamenene (1) by a newly developed enantioselective silane-terminated Heck reaction is described. The Pd0-catalyzed transformation of the allylsilane 7, obtained from 3-(3-methoxy
