168334-05-2Relevant academic research and scientific papers
Syntheses of the Terpenoid Precursors Cyclopent-2-enone and Cyclohex-2-enone Diesters
Kadas, I.,Morvai, V.,Arvai, G.,Toeke, L.,Szoelloesy, A.,et al.
, p. 107 - 118 (2007/10/02)
Two reaction pathways were elaborated for the practical and convenient syntheses of the title compounds.The first route applies a bromination-dehydrobromination sequence to introduce the double bond into 1-alkoxycarbonyl-2-oxocycloalkylacetic and propioni
ARENES FROM ALKANES OR CYCLOALKANES THROUGH DEHYDRATION OR REARRANGEMENT WITH PYRIDINIUM CHLORIDE
Baiocchi, Leandro,Giannangeli, Marilena,Bonanomi, Michele,Picconi, Giuseppe,Ridolfi, Pietro
, p. 199 - 216 (2007/10/02)
The preparations of various kinds of arylacetic acids both from the precursors and from the synthetic equivalents of (2-oxocyclohexenyl)acetic acids are reviewed.Particular attention is paid to the methods by which these intermediates can be obtained since the usefulness of the reaction is obviously bound to substrate availability.Further developments in the field of aromatic hydrocarbons and heterocyclic compounds are illustrated and a model for the reaction is proposed.In addition to the data already published in scientific journals and in the patent literature, several unpublished data are reported.
