168412-13-3Relevant academic research and scientific papers
Synthesis of a novel ring-expanded purine analogue containing a 5:8-fused imidazo[4,5-e][1,2,4]triazocine ring system amidst opportunistic rearrangements and ring transformations
Burnett, Friedrick N,Hosmane, Ramachandra S
, p. 9567 - 9578 (2002)
A novel 5:8-fused heterocycle containing the imidazo[4,5-e][1,2,4]triazocine ring system has been synthesized in ten steps commencing from 1-benzyl-5-methyl-4-nitroimidazole. The compound is a new member of the family of ring-expanded xanthine-xanthosine analogues reported from this laboratory. The synthesis led to the unraveling of a number of novel rearrangements and ring-transformations.
Imidazo[4,5-e][1,2,4]Triazocine: A novel 5:8-fused ring system riddled with rearrangements
Burnett, Friedrick N.,Hosmane, Ramachandra S.
, p. 857 - 861 (2007/10/03)
Attempts to synthesize the title 5:8-fused heterocyclic ring system resulted in a number of novel opportunistic rearrangements and transformations. There is, however, some evidence to believe that one of these rearrangements might proceed through the transient intermediacy of this ring system.
