168414-91-3

Upstream product

• 18226-42-1 1,3,5-Tris(bromomethyl)benzene 
• 108-98-5 thiophenol 
• 168414-97-9 α,α'-dibromo-α''-cyanomesitylene 
• 168414-96-8 3,5-bis[(phenylsulfanyl)methyl]phenol 
• 1070260-71-7 (3,5-Bis-phenylsulfanylmethyl-phenoxy)-tert-butyl-dimethyl-silane 
• 182629-26-1 3,5-bis(chloromethyl)phenol tert-butyldimethylsilyl ether 
• 182629-24-9 dimethyl 5-{[(1,1-dimethylethyl)dimethylsilyl]oxy}benzene-1,3-dicarboxylate 
• 182629-25-0 5-{[(1,1-dimethylethyl)dimethylsilyl]oxy}benzene-1,3-dimethanol 
• 13036-02-7 Dimethyl 5-hydroxyisophthalate 

Downstream Products

• 178438-03-4 [(PdCl(C₆H₅SCH₂)2C₆H₂OCH₂)2C₆H₃CH₂CN] 

Relevant academic research and scientific papers

Self-assembly of hyperbranched spheres

A new type of building block with two coordinatively unsaturated palladium centres has been described that self-assembles in nitromethane solution and disassembles when acetonitrile is added. The resulting hyperbranched, organopalladium spheres have a remarkably narrow size distribution as was evidenced by light-scattering, AFM and TEM measurements. Variation of the structure of the building blocks showed the possibility to vary the size of the self-assembled spheres between 100 and 400 nm.

Kontrolierter Aufbau nanometergrosser, metallorganischer Dendrimere

Stichworte: Dendrimere, Palladiumkomplexe, Supramolekulare Chemie