168609-59-4

Basic information

• Product Name: {1,2-bis(phenylthio)ethane}bromoiodoplatinum(II)
• CAS NO: 168609-59-4
• Molecular Weight: 648.286
• Mol File: 168609-59-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: {1,2-bis(phenylthio)ethane}bromoiodoplatinum(II)(CAS DataBase Reference)
• NIST Chemistry Reference: {1,2-bis(phenylthio)ethane}bromoiodoplatinum(II)(168609-59-4)
• EPA Substance Registry System: {1,2-bis(phenylthio)ethane}bromoiodoplatinum(II)(168609-59-4)

Safety Data

• Hazardous Substances Data: 168609-59-4(Hazardous Substances Data)

Upstream product

• 104975-53-3 {1,2-bis(phenylthio)ethane}dibromoplatinum(II) 
• 68-05-3 tetraethylammonium iodide 
• 14362-44-8 iodide 
• 153660-77-6 {1,2-bis(phenylthio)ethane}chloroiodoplatinum(II) 
• 10097-32-2 bromide 
• 71498-97-0 {1,2-bis(phenylthio)ethane}diiodoplatinum(II) 

Relevant articles and documents

Nucleophilic Displacement of Halides from Dihalogenoplatinum(II) Complexes containing a Chelating Thioether. Kinetics and Equilibria

Kinetic and equilibrium measurements on the displacement of halides from the substrates (X, Y = Cl, Cl; Cl, Br; Br, Br; Br, I; I, I; Cl, I) with the nucleophiles Cl(1-), Br(1-) and I(1-) have been carried out in methanol at 25 deg C, I = 0.5 mol dm3 (LiClO4).The results are discussed in terms of the relative stability of the planar ground and five-co-ordinate transition states, and the lability and kinetic cis effects of co-ordinated halides are compared.All substrates appear to be characterized by a sort of stereoelectronic hindrance leading to retardation effects, mainly in the second-order substitution pathway.