16863-62-0

Basic information

• Product Name: laballenic acid
• CAS NO: 16863-62-0
• Molecular Weight: 280.451
• Mol File: 16863-62-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: laballenic acid(CAS DataBase Reference)
• NIST Chemistry Reference: laballenic acid(16863-62-0)
• EPA Substance Registry System: laballenic acid(16863-62-0)

Safety Data

• Hazardous Substances Data: 16863-62-0(Hazardous Substances Data)

Upstream product

• 66553-46-6 (1E)-1-iodododec-1-ene 
• 53293-00-8 hex-5-ynoic acid 
• 101098-99-1 2-tetradecynal 
• 112-54-9 Dodecanal 
• 37976-62-8 hexadec-2-en-4-yn-1-ol 
• 37976-63-9 hexadeca-3,4-dien-1-ol 
• 105-53-3 diethyl malonate 

Relevant articles and documents

An enantioselective synthesis of (R)-5,6-octadecadienoic acid

A convenient, scalable, and highly enantioselective total synthesis of (R)-5,6-octadecadienoic acid was developed by using the recently established ATA (allenylation of terminal alkynes) reaction of TBS-protected (TBS = tert-butyldimethylsilyl) propargyl alcohol with n-dodecanal in the presence of (R)-α,α-diphenylprolinol as the chiral source. The axial chirality of the allene unit withstood the many common organic transformations that were needed to achieve the total synthesis with a high ee (enantiomeric excess) value.

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